The hydrogen ion concentration of a 10-8 M HCL aqueous solution at 298 K (Kw = 10-14) is:
1.0 x 10-6
1.0525 x 10-7 M
9.525 x 10-8 M
9.525 x 10-8 M
B.
1.0525 x 10-7 M
In aqueous solution of 10-8 M HCl, [H+] is based upon the concentration of H+ ion of 10-8 M HCl and concentration of H+ ion of water Kw of H2O = 10-14 = [H+][OH-] or [H+] = 10-7 M (due to neutral behaviour) os, in aqueous solution of 10-8 M HCl,
[H+] = [H+] of HCl +[H+] of water
= 10-8 + 10-7 = 11 x 10-8 M
1.10 x 10-7 M
Which of the following, not a correct statement?
The electron -deficient molecules can act as Lewis acids
The canonical structures have no real existence
Every AB5 molecules does, in fact, have square pyramid structure
Every AB5 molecules does, in fact, have square pyramid structure
C.
Every AB5 molecules does, in fact, have square pyramid structure
Every AB5 molecule does not, in fact, have square pyramidal structure but AB5 molecules have trigonal bipyramidal structures due to sp3d hybridisation.
HgCl2 and I2 both when dissolved in water containing I– ions the pair of species formed is
HgI2 , I3-
Hgl2, I-
HgI43-, I3-
HgI43-, I3-
C.
HgI43-, I3-
In a solution containing HgCl2, I2 and I–, both HgCl2 and I2
compete for I–.
Since formation constant of [HgI4]2– is 1.9 × 1030
which is very large as compared with I3– (Kf= 700)
therefore, I– will preferentially combine with HgCl2
HgCl2 + 2l- → Hgl2↓ + 2Cl-
Hgl2 + 2l- → [Hgl4]2-
The most stable carbonium ion among the following is
C.
Due to more possibility for delocalisation in
When 750 mL of 0.5 M HCl is mixed with 250 mL of 2 M NaOH solution, the value of pH will be
pH = 7
pH > 7
pH < 7
pH = 0
B.
pH > 7
nHCl = MHCl x VHCl and nNaOH = MNaOH x VNaOH
where n = number of moles
M = molarity, V = volume
∴ nHCl = 0.5 x 750 = 375 milimoles
nNaOH = 2.0 x 250 = 500 milimoles
∵ nNaOH > nHCl
The solution is basic and has pH > 7